[Photoshop] Why does it change the color white?

[Prest]

So here's what the image looks like in paint

And here's what it looks like in photoshop

However once I save the picture and upload it to a normal website it does look white again, so it's just in the interface of photoshop, its CS5, anybody know how to fix it?

 

[Peroxide]

Color mode?

 

[Prest]

RGB Color

 

[Resource]

Print screen and send your "File-New" window.

 

[Prest]

Fixed it

My monitor is a dell so...