Linux Virtual Hosts Debian

[Radium]

Okay, so i currently own a dedicated server running Debian.
I just added a additional IP to it, and not quite sure how to make use of it!

Goal - To run a website & server from the IP separate from the original server.

So lets say 69.xx.xx.xx runs Server A and Website A
The additional IP = 200.xx.xx.xx

So, the first thing i needed to do was add a virtual host. Which i think i did correctly..

/etc/network/interfaces includes this

auto lo
iface lo inet loopback

auto eth0 eth0:1
iface eth0 inet static
  address 69.xx.xx.xx
  network 69.xx.xx.xx
  netmask 255.255.255.xxx
  broadcast 69.xx.xx.xx
  gateway 69.xx.xx.xx

iface eth0:1 inet static
  address 200.xx.xx.xx
  netmask 255.255.255.xxx
  broadcast 200.xx.xx.xx

Hopefully that is right? "ifconfig" outputs

eth0:1    Link encap:Ethernet  HWaddr 00:xx:xx:xx:xx:xx
          inet addr:200.xx.xx.xx  Bcast:200.xx.xx.xx  Mask:255.255.255.xxx
          UP BROADCAST RUNNING MULTICAST  MTU:1500  Metric:1
          Interrupt:16 Memory:fa000000-fa012800

So 69.xx.xx.xx Points to /var/www/website1
i want to point 200.xx.xx.xx to /var/www/website2

So this is in my httpd.conf

NameVirtualHost 200.xx.xx.xx
<VirtualHost 200.xx.xx.xx>
    ServerName www.website2.com
    DocumentRoot /var/www/website2
</VirtualHost>

Is this even right?
What would be required to complete the Goal?
How would i point the OT server to the virtual host IP?

Thanks